Osmotic coefficients of non-aqueous electrolyte solutions at thermodynamic and McMillan-Mayer level

Abstract

Precise osmotic coefficients from absolute vapor pressure measurements on various electrolyte solutions of organic solvents are given as the reference data for use in relative vapor pressure measurement methods. The availability of reliable data is used for a study of the interdependence of thermodynamic properties and theoretical and experimental McMillan-Mayer level methods, such as chemical model and hypernetted chain calculations and small angle neutron scattering experiments. © 1993, Walter de Gruyter GmbH.