X-ray absorption study of ceria nanorods promoting the disproportionation of hydrogen peroxide

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Abstract

A quasi in situ X-ray absorption study demonstrated that the disproportionation of hydrogen peroxide (H2O2) promoted by ceria nanorods was associated with a reversible Ce3+/Ce4+ reaction and structural transformations in ceria. The direction of this reversible reaction was postulated to depend on the H2O2 concentration and the fraction of Ce3+ species in ceria nanorods.

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Wu, T. S., Zhou, Y., Sabirianov, R. F., Mei, W. N., Soo, Y. L., & Cheung, C. L. (2016). X-ray absorption study of ceria nanorods promoting the disproportionation of hydrogen peroxide. Chemical Communications, 52(28), 5003–5006. https://doi.org/10.1039/c5cc10643e

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