Effects of K+, Mg2+, Ca2+, Zn2+, La3+, Cr3+, Ce3+, Ce4+, and Mo5+ Doping on the Adsorption Performance and Optical Properties of Sodium Titanate Nanotubes

Abstract

Metal-doped titanate nanotubes (TNTs) were synthesized using a simple ion-exchange method. Cations with different valencies (Mg2+, Ca2+, Zn2+, K+, Cr3+, Ce3+, Ce4+, Mo5+, and La3+) were used to assess their effects on the adsorption performance and optical properties of the prepared nanotubes. All samples were characterized by X-ray powder diffraction (XRD), field-emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDXS), and elemental mapping, and the optical properties were analyzed using photoluminescence (PL) spectroscopy. The adsorption performance of the prepared doped titanate nanotubes was tested against methylene blue (MB) as a model cation dye. The results revealed that all samples except Ce(IV)-TNT showed high removal efficiencies but at different equilibrium times. Mg-TNT, Zn-TNT, and K-TNT showed higher MB removal percentages (97%) after 45 min, while Ca-TNT, Cr-TNT, Ce(III)-TNT, Mo-TNT, La-TNT, and Na-TNT showed removal efficiencies of 95, 84, 95, 96, 94, and 96% after 65, 1200, 120, 300, 180, and 105 min, respectively. The titanate nanotubes were recycled by photocatalytic degradation of the adsorbed dye molecules. The band gaps, valence band, and conduction band were calculated and compared for the potential photocatalytic water splitting application.