The article represents a review of the chemistry of transition metal complexes containing the boryl (-BX2) ligand based on the chemical literature published up to and including the calendar year 2006. A brief compendium of papers published in the year 2007 is also included. Notwithstanding the ever-growing volume of literature detailing useful organic transformations in which these complexes have been implicated (e.g. C-H activation, hydroboration, diboration), the primary focus of this article is a review of issues of structure and bonding in boryl systems. Thus, the evidence for boryl ligands acting - to a greater or lesser extent - as sigma donors and/or pi acceptors is examined at length, as are issues relating to secondary interactions (e.g with hydride co-ligands) within the metal coordination sphere, and the consequent relationship to borane sigma complexes. © 2008 Springer-Verlag.
CITATION STYLE
Kays, D. L., & Aldridge, S. (2008). Transition metal boryl complexes. Structure and Bonding. https://doi.org/10.1007/430_2007_079
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