Local-and intermediate-range atomic structures were investigated on amorphous phases of an ordinary phase-change material, Ge2Sb2Te5 (GST), and an exotic one, Cu2GeTe3 (CGT), by using anomalous X-ray scattering close to K absorption edges of each element to find a fast amorphous-crystalline phase-change mechanism. The obtained data were analyzed by using reverse Monte Carlo modeling to obtain partial structure factors, partial pair distribution functions, and threedimensional atomic configurations. Ring statistics were carefully examined to clarify the similarity and difference compared with the corresponding crystal structures, and it was found that amorphous GST has a number of fourmembered rings indicating fragments of crystal structure, and amorphous CGT has a remarkable number of threemembered rings showing a collapse of crystal structures composed of purely six-membered rings. A persistent homology analysis was carried out and long-range ring structures of the constituent elements were observed in the amorphous phase, which may originate from fragments of crystal structures with a long-range periodicity. 2020
CITATION STYLE
Stellhorn, J. R., Hosokawa, S., & Kohara, S. (2020). Local-and intermediate-range structures on ordinary and exotic phase-change materials by anomalous x-ray scattering. Analytical Sciences, 36(1), 5–16. https://doi.org/10.2116/analsci.19SAR02
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