Removal of Chromium (VI) and Lead (II) from Aqueous Solution Using Domestic Rice Husk Ash-(RHA-) Based Zeolite Faujasite

Abstract

Rice husk ash (RHA), is a widely available biobased source for high purity silica. In this work, zeolite Faujasite (FAU) is synthesized using extracted silica from RHA (collected from a local region of Bangladesh). The synthesized zeolite FAU was used as an adsorbent for Cr(VI) and Pb (II) batch-wise adsorptive removal from respective aqueous solution. The synthesized zeolite FAU was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), nitrogen-sorption, and Fourier transfer infrared (FT-IR) spectroscopy. Metal ion adsorption studies were performed by varying metal concentration (20-100 mg/L for Cr(VI) and 900-133 mg/L for Pb(II)), sorbent dosage (2-10 g/L for chromium and 0.5-1.5 g/L for lead), and contact time (10-120 min for both metal ions). The maximum adsorption capacity of RHA-based zeolite FAU was found to be 3.56 mg/g and 342.16 mg/g for Cr(VI) and Pb(II), respectively. Since the sorption data was found to match with Langmuir isotherm, a monolayer adsorption was occurred. The regeneration of the RHA-based zeolite FAU by NaCl solution showed the potential of repeated as well as continuous operation.