Anthracene-Based Fluorophore and Its Re(I) Complexes: Investigation of Electrical Properties and Schottky Diode Behavior

Abstract

A novel fluorophore (HL) [1-((E)-(quinolin-8-ylimino)methyl)anthracen-2-ol] using a suitably designed anthrol and quinoline derivative was synthesized and well characterized. Then, two Re(I) complexes with the fac-[Re(CO)3]+ moiety were prepared with the ligand under different reaction conditions. Both the complexes [Re(L)(CO)3] (1) and [Re(HL)(CO)3Cl] (2) absorbed in the visible region. Steady-state fluorescence measurements and time-correlated single-photon count experiments were performed to elucidate the nature of the excited state. The ground- and excited-state geometries were theoretically investigated using density functional theory (DFT) calculations. The electrical properties of the ligand and the complexes have been explored with the help of a sandwich-structured thin-film device of an Al/sample/indium tin oxide (ITO) configuration at room temperature. The thermionic emission (TE) theory was adopted for the extraction of Schottky diode parameters such as ideality factor, barrier height, and series resistance. Further, the space-charge-limited current (SCLC) theory was employed for a better understanding of the charge transport phenomenon.