Performance and Efficiency of Anionic Dishwashing Liquids with Amphoteric and Nonionic Surfactants

Abstract

Performance and efficiency of anionic [sodium lauryl ether sulfate (SLES) and sodium α-olefin sulfonate (AOS)] and amphoteric [cocamidopropyl betaine (CAB)] as well as nonionic [cocodiethanol amide (DEA), various ethoxylated alcohols (C12-C15-7EO, C10-7EO and C9-C11-7EO) and lauramine oxide (AO)] surfactants in various dishwashing liquid mixed micelle systems have been studied at different temperatures (17.0, 23.0 and 42.0 °C). The investigated parameters were critical micelle concentration (CMC), surface tension (γ), cleaning performance and, foaming, biodegradability and irritability of anionic (SLES/AOS) and anionic/amphoteric/nonionic (SLES/AOS/CAB/AO) as well as anionic/nonionic (SLES/AOS/DEA/AO, SLES/AOS/C12-C15-7EO/AO, SLES/AOS/C10-7EO/AO and SLES/AOS/C9-C11-7EO/AO) dishwashing surfactant mixtures. In comparison to the starting binary SLES/AOS surfactant mixture, addition of various nonionic surfactants promoted CMC and γ lowering, enhanced cleaning performance and foaming, but did not significantly affect biodegradability and irritability of dishwashing formulations. The anionic/nonionic formulation SLES/AOS/C9-C11-7EO/AO shows both the lowest CMC and γ as well as the best cleaning performance, compared to the other examined dishwashing formulations. However, the results in this study reveal that synergistic behavior of anionic/nonionic SLES/AOS/ethoxylated alcohols/AO formulations significantly improves dishwashing performance and efficiency at both low and regular dishwashing temperatures (17.0 and 42.0 °C) and lead to better application properties.