How a supercooled liquid borrows structure from the crystal

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Abstract

Using computer simulations, we establish that the structure of a supercooled binary atomic liquid mixture consists of common neighbor structures similar to those found in the equilibrium crystal phase, a Laves structure. Despite the large accumulation of the crystal-like structure, we establish that the supercooled liquid represents a true metastable liquid and that liquid can "borrow"the crystal structure without being destabilized. We consider whether this feature might be the origin of all instances of liquids with a strongly favored local structure.

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Pedersen, U. R., Douglass, I., & Harrowell, P. (2021). How a supercooled liquid borrows structure from the crystal. Journal of Chemical Physics, 154(5). https://doi.org/10.1063/5.0033206

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