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Catalytic Dihydroxylation of Olefins with Hydrogen Peroxide: An Organic-Solvent- and Metal-Free System

Angewandte Chemie - International Edition (2003) 42(45) 5623-5625
DOI: 10.1002/anie.200352568
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Abstract

Green and convenient: Olefins are oxidized to 1,2-diols in high yield with 30% H2O2 in the presence of resin-supported sulfonic acid (see scheme) under metal-free conditions without any organic solvent. The catalyst can be recycled easily and is effective for at least 10 cycles.

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Usui, Y., Sato, K., & Tanaka, M. (2003). Catalytic Dihydroxylation of Olefins with Hydrogen Peroxide: An Organic-Solvent- and Metal-Free System. Angewandte Chemie - International Edition, 42(45), 5623–5625. https://doi.org/10.1002/anie.200352568

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