Nickel-catalysed carboxylation of organoboronates

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Abstract

A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility. 2014 © The Royal Society of Chemistry.

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Makida, Y., Marelli, E., Slawin, A. M. Z., & Nolan, S. P. (2014). Nickel-catalysed carboxylation of organoboronates. Chemical Communications, 50(59), 8010–8013. https://doi.org/10.1039/c4cc03650f

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