Formation of an imino-stabilized cyclic tin(II) cation from an amino(imino)stannylene

Abstract

The novel amino(imino)stannylene 1 was prepared by conversion of HNIPr (NIPr=bis(2,6-diisopropylphenyl)imidazolin-2-imino) with one equivalent of Lappert's tin reagent (Sn[N(SiMe 3) 2 ] 2). Treatment of 1 with DMAP (4-dimethylaminopyridine) yields its Lewis acid-base adduct 2. The reaction of 1 with one equivalent of trimethylsilyl azide results in replacement of the amino group at the tin center by an N 3 substituent with concomitant elimination of N(SiMe 3) 3 to afford dimeric [N 3 SnNIPr] 2 (3). Remarkably, the reaction of 1 with B(C 6 F 5) 3 produces the novel tin(II) monocation 4 + [MeB(C 6 F 5) 3 ] - comprising a four-membered stannacycle through methyl-abstraction from the trimethylsilyl group.