Phosphate of aluminum as corrosion inhibitor for steel in H3PO4

Abstract

The influence of phosphate of aluminum (PA) on the corrosion inhibition of mild steel in phosphoric acid solution was studied using the weight-loss method. The electrochemical performance of the inhibitors was also investigated through potentiodynamic polarisation and EIS measurements. The inhibition efficiency of inhibitor increases with concentration to attain 84 % at 10-2M of PA in 0.33 M H3PO4. Polarization studies show that PA is a mixed-type inhibitor and acts both on the cathodic and anodic reactions without changing the mechanism of the hydrogen evolution reaction. The inhibition efficiency of PA is temperature-dependent in the range 298-363 K, the associated activation energy has been determined. PA adsorbs on the steel surface according to a Langmuir isotherm adsorption model.