Abstract
A series of Au(i)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(ii) structure.
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CITATION STYLE
APA
Hidalgo, N., de la Cruz-Martínez, F., Martín, M. T., Nicasio, M. C., & Campos, J. (2022). A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation. Chemical Communications, 58(65), 9144–9147. https://doi.org/10.1039/d2cc03089f
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