Probing Photodynamics of Retinal Protonated Schiff-Base with 7 fs Impulsive Vibrational Spectroscopy

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Abstract

Two and three pulses experiments are conducted to record the elusive S1 vibrational spectrum of Retinal Protonated Schiff-Base in solution. We find a reduction in C=C stretching frequency and other shifted bands in the fluorescent state, whose relevance are discussed.

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Bismuth, O., Wand, A., Friedman, N., Sheves, M., & Ruhman, S. (2009). Probing Photodynamics of Retinal Protonated Schiff-Base with 7 fs Impulsive Vibrational Spectroscopy. In Springer Series in Chemical Physics (Vol. 92, pp. 589–591). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-540-95946-5_191

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