Aspect ratio-controlled preparation of α-CaSO4·0.5H2O from phosphogypsum in potassium tartrate aqueous solution

Abstract

In this study, a simple and efficient strategy is developed to synthesize rod-shaped α-CaSO4·0.5H2O crystals with tunable aspect ratio from industrial phosphogypsum only in potassium tartrate aqueous solution at a low temperature. Industrial phosphogypsum can be effectively converted into rod-shaped α-CaSO4·0.5H2O crystals with the assistance of potassium tartrate, and the aspect ratio of α-CaSO4·0.5H2O crystals gradually decreases from 52:1 to 1:1 with increasing the concentration of potassium tartrate. The formation process of the rod-shaped α-CaSO4·0.5H2O crystals in this system involves the dissolution of CaSO4·2H2O and nucleation of α-CaSO4·0.5H2O crystals. The tartrate ions from potassium tartrate in this system preferentially bind to (001) and (002) facets of α-CaSO4·0.5H2O crystals, inhibiting the growth of α-CaSO4·0.5H2O crystals along the c-axis and controlling its morphology and aspect ratio.