Radical cyclization reactions at a peri position were used for the synthesis of polyaromatic compounds. Depending on the choice of reaction conditions and substrate, this flexible approach led to Bu 3 Sn‐substituted phenalene, benzanthrene, and olympicene derivatives. Subsequent reactions with electrophiles provided synthetic access to previously inaccessible functionalized polyaromatic compounds.
CITATION STYLE
Tsvetkov, N. P., Gonzalez‐Rodriguez, E., Hughes, A., dos Passos Gomes, G., White, F. D., Kuriakose, F., & Alabugin, I. V. (2018). Radical Alkyne peri ‐Annulation Reactions for the Synthesis of Functionalized Phenalenes, Benzanthrenes, and Olympicene. Angewandte Chemie, 130(14), 3713–3717. https://doi.org/10.1002/ange.201712783
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