Supramolecular engineering with macromolecules: An alternative concept for block copolymers

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Abstract

Metallo-supramolecular AB block copolymers are the first examples of macromolecular engineeering. A new concept for the formation of block copolymers by a supramolecular approach is presented. For this purpose the authors utilized an asymmetrical bis(terpyridine)-ruthenium complex as the supramolecular linkage between the two blocks (see figure).

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Lohmeijer, B. G. G., & Schubert, U. S. (2002). Supramolecular engineering with macromolecules: An alternative concept for block copolymers. Angewandte Chemie - International Edition, 41(20), 3825–3829. https://doi.org/10.1002/1521-3773(20021018)41:20<3825::AID-ANIE3825>3.0.CO;2-6

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