Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50°C generates α-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters. © 2005 by MDPI.
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Sueda, T., Takeuchi, Y., Suefuji, T., & Ochiai, M. (2005). Addition to electron deficient olefins of α-oxy carbon-centered radicals, generated from cyclic ethers and acetals by the reaction with alkylperoxy- λ3-iodane. Molecules, 10(1), 195–200. https://doi.org/10.3390/10010195