Potential of mild torrefaction for upgrading the wood energy value of different Eucalyptus species

Abstract

Torrefaction is a promising pre-treatment for improving the fuel quality of biomass. This study examined the effect of a mild torrefaction (from 160 to 230 °C) on the heating value, elemental composition, and thermogravimetric analysis of wood from eight Eucalyptus species (E. botryoides Sm., E. globulus Labill., E. grandis W.Hill ex Maiden, E. maculata (Hook.) K.D. Hill & L.A.S.Johnson, E. propinqua Maiden Deane, E. rudis Endl., E. saligna Sm., and E. viminalis Labill.). The higher heating values (HHV) increased from the initial average of 19 MJ kg-1 to 21 MJ kg-1 in the torrefied samples. The carbon content increased from 48.2% to 53.3% and the C/O ratio from 1.08 to 1.35. The torrefied wood samples showed more thermal stability with a shift of the mass loss peaks to higher temperatures and a higher residual mass at 450 °C of 36%, in comparison to 30% of the untreated samples. Torrefaction concentrated the biomass samples in the more energetic and thermal resistant components and decreased their sulfur and chlorine content, leading to a better combustion performance. The wood of the eight Eucalyptus species had a similar behavior and showed quality improvement. Therefore, torrefaction showed potential as a pre-treatment for eucalyptus biomass fuel improvement.