Vibrorotational Raman and infrared spectra of polar diatomic molecules in inert solutions. III. Isotropic and anisotropic Raman spectra of HCl in liquid SF6

Abstract

Vibrorotational Raman and infrared spectra of diluted HCl in liquid SF6 was analyzed. Non-Markovian spectral theory was employed to calculate the theoretical profiles. Qualitative and quantitative analyses of the memory and interference effects in the Raman spectra demonstrated the intra-branch, inter-branch and cancellation mixing effects along the different relaxation channels.