Isotope Labeling Reveals Fast Atomic and Molecular Exchange in Mechanochemical Milling Reactions

14Citations
Citations of this article
37Readers
Mendeley users who have this article in their library.
Get full text
This PDF is freely available from an open access repository. It may not have been peer-reviewed.

Abstract

Using tandem in situ monitoring and isotope-labeled solids, we reveal that mechanochemical ball-milling overcomes inherently slow solid-state diffusion through continuous comminution and growth of milled particles. This process occurs with or without a net chemical reaction and also occurs between solids and liquid additives that can be practically used for highly efficient deuterium labeling of solids. The presented findings reveal a fundamental aspect of milling reactions and also delineate a methodology that should be considered in the study of mechanochemical reaction mechanisms.

Cite

CITATION STYLE

APA

Lukin, S., Tireli, M., Stolar, T., Barišić, D., Blanco, M. V., Di Michiel, M., … Halasz, I. (2019). Isotope Labeling Reveals Fast Atomic and Molecular Exchange in Mechanochemical Milling Reactions. Journal of the American Chemical Society, 141(3), 1212–1216. https://doi.org/10.1021/jacs.8b12149

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free