Abstract
Metal-organic nanoparticles (see SEM image) showing valence-tautomeric behavior have been obtained by a versatile approach involving precipitation and coordination polymerization. They undergo reversible temperature-dependent interconversion between low- and high-spin forms, as revealed by plotting the magnetic moment χ as a function of temperature. (Graph Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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Imaz, I., Maspoch, D., Rodríguez-Blanco, C., Pérez-Falcón, J. M., Campo, J., & Ruiz-Molina, D. (2008). Valence-tautomeric metal-organic nanoparticles. Angewandte Chemie - International Edition, 47(10), 1857–1860. https://doi.org/10.1002/anie.200705263
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