Abstract
Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry allowed the direct determination of the extent of macrocyclic and linear oligomer formation in the palladium(0)-catalyzed allylation of highly acidic and non-nucleophilic arenesulfonamides, sulfamide, and cyanamide. Palladium-containing 15-membered-ring macrocyclic compounds gave unusual [M - H]+ ions besides [M + Na]+ and [M + K]+ adducts.
Cite
CITATION STYLE
Cerezo, S., Cortés, J., Galvan, D., López-Romero, J. M., Moreno-Mañas, M., Pleixats, R., … Roglans, A. (1999). Application of matrix-assisted laser desorption/ionization time-of-flight mass spectrometry to the structure determination of medium and large macrocycles formed by palladium(0)-catalyzed allylation of arenesulfonamides, sulfamide, and cyanamide. Rapid Communications in Mass Spectrometry, 13(23), 2359–2365. https://doi.org/10.1002/(SICI)1097-0231(19991215)13:23<2359::AID-RCM799>3.0.CO;2-9
Register to see more suggestions
Mendeley helps you to discover research relevant for your work.
