Characterization of β′ phase precipitates in an Mg-5at%Gd alloy aged in a peak hardness condition, studied by high-angle annular detector dark-field scanning transmission electron microscopy

Abstract

The β′ phase precipitated in a 95 at%Mg-5 at%Gd (Mg 95Gd5) alloy aged in a peak hardness condition (at 200°C for 100hrs) is studied by high-angle annular detector dark-field scanning transmission electron microscopy (HAADF-STEM). Atomic-scaled HAADF-STEM observations of the β′ phase can propose a new structure model with an orthorhombic unit cell of a = 0.64nm, b = 2.28nm and c = 0.52 nm and a composition of Mg7Gd. The β′ precipitates have a plate-shape with an about 40 nm width along the [001]m of the Mg-matrix and an about 100 nm length along [210]m-typed directions, and joining of the plate-shaped precipitates establishes a two-dimensional cell structure parallel to the (001)m plane of the Mg-matrix. © 2006 The Japan Institute of Metals.