We present the reactivity of the Mg-C and the β-CH bonds in the trigonal pyramidal [(pmdta)Mg(nBu)]+ exhibiting a weak Mg⋯F interaction with counter anion, [B(C6F5)4]−. Instantaneous β-hydride reactivity with benzophenone, reductive alkylation of phenyl benzoate, and straightforward synthesis of [(pmdta)MgH]+via metathesis with pinacolborane/phenylsilane are discussed.
CITATION STYLE
Ankur, N., Sharma, D., Andrews, A. P., & Venugopal, A. (2023). Reactivity of a quasi-four-coordinate butylmagnesium cation. Dalton Transactions, 52(6), 1533–1537. https://doi.org/10.1039/d3dt00018d
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