A modular synthetic approach is reported for the synthesis of heterometallic metal-organic complex arrays (MOCAs). Modules of four metal centers containing three different metals copper(II), nickel(II), platinum(II), or ruthenium(II) are prepared using a solid-phase polypeptide synthesis technique and then linked in solution to make MOCAs of eight metal centers as linear, T-branched, and H-branched compounds. The MOCA molecular topologies thus have specific unique linear and branched sequences of metals along the peptide backbone.
CITATION STYLE
Sajna, K., Fracaroli, A. M., Yaghi, O. M., & Tashiro, K. (2015). Modular synthesis of metal-organic complex arrays containing precisely designed metal sequences. Inorganic Chemistry, 54(4), 1197–1199. https://doi.org/10.1021/ic5025372
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