An electrocatalytic activity of auceo2/carbon catalyst in fuel cell reactions: Oxidation of borohydride and reduction of oxygen

Abstract

This paper describes the investigation of electrocatalytic activity of the AuCeO2/C catalyst, prepared using the microwave irradiation method, towards the oxidation of sodium borohydride and oxygen reduction reactions in an alkaline medium. It was found that the obtained AuCeO2/C catalyst with Au loading and electrochemically active surface area of Au nanoparticles (AuNPs) equal to 71 µg cm−2 and 0.05 cm2, respectively, showed an enhanced electrocatalytic activity towards investigated reactions, compared with the Au/C catalyst with an Au loading and electrochemically active surface area of AuNPs equal to 78 µg cm−2 and 0.19 cm2, respectively. The AuCeO2/C catalyst demonstrated ca. 4.5 times higher current density values for the oxidation of sodium borohydride compared with those of the bare Au/C catalyst. Moreover, the onset potential of the oxygen reduction reaction (0.96 V) on the AuCeO2/C catalyst was similar to the commercial Pt/C (0.98 V).