Organically Functionalized Mesoporous SBA-15 Type Material Bearing Fluorescent Sites for Selective Detection of HgII from Aqueous Medium

Abstract

Hg(II) contamination in water resources is one of the major health issues in keeping the purity standard of the municipal water supply. Herein, we report a new mesoporous sensor probe material SBA-ABZ-PEA having a 2D-hexagonally ordered mesoporous framework bearing covalently bonded fluorescent sites, and this has been synthesized through a two-step post-synthesis grafting route. A pure silica mesoporous SBA-15 material has been functionalized with (3-chloropropyl)triethoxysilane (ClPTES) to obtain chloro-functionalized SBA-15, which was further reacted with 4-aminobenzaldehyde followed by treatment with 2-(2-pyridyl)-ethylamine resulting in functionalized 2D-hexagonal mesoporous sensor probe SBA-ABZ-PEA. Small angle PXRD, N2 adsorption/desorption, HRTEM, TGA, and FT-IR studies have been carried out to characterize these materials. Our experimental results suggested successful grafting of the organic moiety on the SBA-15 surface along with preservation of mesoporosity throughout the grafting process. Photoluminescence measurements were carried out in the aqueous suspension of SBA-ABZ-PEA in the presence of different metal cations, like NaI, MgII, AlIII, KI, CaII, MnII, CoII, CuII, ZnII, CdII, PbII, and HgII. This result revealed that, among the various metal-ions, the emission intensity of the mesoporous sensing probe material SBA-ABZ-PEA has been dramatically quenched in the presence of the HgII ion. To check the sensitivity of the sensor probe, the fluorescence emission was also studied in the presence of different concentrations of HgII ions. A perfect linear plot between the concentrations of HgII ions in the aqueous medium with their corresponding fluorescence intensities with a detection limit of 1.2 × 10-6 M has been observed.