The sequential ethenolysis, transesterification and hydrogenation of a model unsaturated renewable oil for the preparation of potential biofuels is reported herein. Ethenolysis conversions of up to 70%, using olive oil, were obtained applying a relatively low 2 bar ethylene pressure and toluene as solvent. The ethenolyzed olive oil was quantitatively transesterified with methanol and, subsequently, hydrogenated with molecular hydrogen over Pd/C, affording access to novel biofuel compositions, including different fractions of biogasoline, biokerosene and biodiesel.
CITATION STYLE
Lima, P. S., Ferreira, L. A., Freitas, L. H., Rheinheimer, M. W., Sokolovicz, Y. C. A., & Schrekker, H. S. (2014). Unsaturated renewable oil transformation into novel biofuel compositions via an olefin metathesis-transesterification-hydrogenation sequence. Journal of the Brazilian Chemical Society, 25(12), 2266–2271. https://doi.org/10.5935/0103-5053.20140208
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