This study investigated the interaction of Fe(II) ions with esmeraldine salt form of polyaniline (PANI-ES). Treatment of the aniline with ammonium persulfate in an acidic medium generated the polymer, which was doped with iron ion through the addition of the salt Fe(NH4)2(SO4)2·6H2O in amounts equimolar a room temperature. Xray diffraction, infrared and Mössbauer spectroscopies were used to characterize the doped polymer. Through the set of spectroscopic results it was possible to confirm the formation of PANI-Fe (II) complex and that these ions interacted with the benzenoids nitrogen atoms of the polymer chain.
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Filho, Y. F., Filho, E. N., Dos Santos, V. M., & Da Silva Filho, E. A. (2015). Interaction of ion iron(II) with polyaniline observed by infrared spectroscopy, X-ray and Mössbauer spectroscopy. Revista Virtual de Quimica, 7(6), 2487–2496. https://doi.org/10.5935/1984-6835.20150148