Abstract
The electro-oxidative polymerization of an enantiopure chiral 3,4-ethylenedioxythiophene monomer, performed using spin-polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the chiral-induced spin selectivity effect.
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APA
Tassinari, F., Amsallem, D., Bloom, B. P., Lu, Y., Bedi, A., Waldeck, D. H., … Naaman, R. (2020). Spin-Dependent Enantioselective Electropolymerization. Journal of Physical Chemistry C, 124(38), 20974–20980. https://doi.org/10.1021/acs.jpcc.0c06238
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