Stereoselective C,C-bond formation. Cyclizations of biradicals

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Abstract

The formation of C,C-bonds via photolytically generated biradicals can occur with high stereoselectivity. If triplet biradicals are involved, chiral induction is highly likely. Syntheses that occur only via singlet biradicals have a good chance to show a memory effect of chirality.

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Giese, B., Barbosa, F., Stähelin, C., Sauer, S., Wettstein, P., & Wyss, C. (2000). Stereoselective C,C-bond formation. Cyclizations of biradicals. In Pure and Applied Chemistry (Vol. 72, pp. 1623–1629). Walter de Gruyter GmbH. https://doi.org/10.1351/pac200072091623

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