Controls on authigenic carbonate precipitation at cold seeps along the convergent margin off Costa Rica

Abstract

Five sediment cores from cold seeps at the forearc off Costa Rica were used to explore the relationship between fluid advection, dissolved Ca concentrations in upward migrating fluids, and authigenic CaCO 3 precipitation. A numerical transport-reaction model was used to determine rates of anaerobic oxidation of methane (AOM), CaCO 3 precipitation, and benthic fluxes of solutes. Production of carbonate alkalinity and formation of authigenic carbonates is most intense at intermediate flow rates (3-40 cm a -1) and reduced under low and high flux conditions (0.1 and 200 cm a -1). Dissolved Ca concentrations observed in the vent fluids off Costa Rica cover a wide range between 4 and 31 mM, clearly exceeding seawater concentrations at two locations. Systematic model runs showed that high Ca concentrations in ascending fluids enhance the rate of authigenic carbonate production at moderate flow rates leading to an almost quantitative fixation of deeply derived Ca in authigenic carbonates. Hence, CaCO 3 precipitation is not only controlled by Ca diffusing into the sediment from bottom water, but also by the Ca concentration in ascending fluids. Thus, Ca enriched fluids offer a reason for enhanced subsurface CaCO 3 precipitation and the occurrence of carbonate caps on dewatering structures in the Central American fore-arc. Based on average precipitation rates deduced from the systematic model runs it is possible to give a rough estimate of the global Ca-fixation at cold seeps (∼210 10 mol Ca a -1), which suggests that cold seeps are most likely not of key importance with respect to Ca cycling in the ocean. Copyright 2010 by the American Geophysical Union.