Unusual Regioselectivity in the Reaction of Allyl‐ or Allenylpropargyltitanium Compounds with Carbonyl Compounds: An Efficient Synthesis of Alkylidenecyclopropane Derivatives

  • Kasatkin A
  • Sato F
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Abstract

Steric strain shifts the equilibrium between the two isomeric allyltitaniumcompounds and isomeric allenyl- and propargyltitanium compounds containingcyclopropane units. This leads additions to electrophilic carbonylcompounds and thus provides easy access to alkylidencyclopropanederivatives.

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Kasatkin, A., & Sato, F. (1996). Unusual Regioselectivity in the Reaction of Allyl‐ or Allenylpropargyltitanium Compounds with Carbonyl Compounds: An Efficient Synthesis of Alkylidenecyclopropane Derivatives. Angewandte Chemie International Edition in English, 35(23–24), 2848–2849. https://doi.org/10.1002/anie.199628481

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