Supersaturation and Critical Size of Cloud Condensation Nuclei in Marine Stratus Clouds

Abstract

Observations of marine stratus clouds in clean air off the Californian coast reveal a functional relationship between the number of cloud condensation nuclei (CCN) and supersaturation. Satellite-derived liquid droplet density estimates the number density of CCN. Combining the estimated supersaturation using Köhler theory, global maps of supersaturation and the critical activation size of CCN are estimated. Here, we show that high supersaturation >0.5% persists over the oceans with a critical CCN size of 25–30 nm, which is smaller than the conventional wisdom of 60 nm. Independent support for such high supersaturation in the marine cloud is obtained from CCN measurements provided by the “Atmospheric Tomography Mission.” Higher supersaturation implies smaller activation size for CCN making cloud formation more sensitive to changes in aerosol nucleation.