Abstract
Two novel polyazines were successfully synthesized via palladium-catalyzed Suzuki coupling method of N,N'-bis(5-bromothiophene)-2-aldehyd azine with 2,5-thiophenediboronic acid and 9,9-dioctylfluorene-2,7-diboronic acid, respectively. The polymers were characterized by 1H-NMR, FT-IR and UV-VIS spectroscopy. The thermal properties of the polymers were investigated by TGA analysis. The semi-crystalline structure of these compounds was demonstrated by X-ray diffraction study.
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Mihai, I., Ivanoiu, M., Vacareanu, L., & Grigoras, M. (2011). Suzuki polycondensation: A simple way for synthesis of new polyazines containing thiophene and fluorene moieties. E-Polymers. https://doi.org/10.1515/epoly.2011.11.1.352
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