Synthesis and Characterization of Novel Peripherally 3-Bromo-1-Phenyl-1-Propene Derivative of Porphyrazine

Abstract

Magnesium porphyrazines substituted with eight (phenyl-propene) groups on the peripheral positions have been prepared by cyclotetramerization of 1,2-bis(3-phenyl-2-propenethio) maleonitrile and then achieved porphyrazine by 3-bromo-1-phenyl-1-propene. Metal-free derivative was obtained by its treatment with trifluoroacetic acid. The new compounds have been characterized by FT-IR, (1)H-NMR, UV-VIS and elemental analysis methods.