The chemical composition and mixing state of BC-containing particles and the implications on light absorption enhancement

Abstract

The radiative forcing of black carbon (BC) depends strongly on its mixing state in different chemical environments. Here we analyzed the chemical composition and mixing state of BC-containing particles by using a single-particle aerosol mass spectrometer and investigated their impact on light absorption enhancement (Eabs) at an urban (Beijing) and a rural site (Gucheng) in the North China Plain. While the BC was dominantly mixed with organic carbon (OC), nitrate, and sulfate at both the urban and rural sites, the rural site showed a much higher fraction of BC coated with OC and nitrate (36;% vs. 15;%-20;%). Moreover, the BC mixing state evolved significantly as a function of relative humidity (RH), with largely increased coatings of OC-nitrate and nitrate at high RH levels. By linking with an organic aerosol (OA) composition, we found that the OC coated on BC comprised dominantly secondary OA in Beijing, while primary and secondary OA were similarly important in Gucheng. Furthermore, Eabs was highly dependent on secondary inorganic aerosol coated on BC at both sites, while the coated primary OC also resulted in an Eabs of g1/4;1.2 for relatively fresh BC particles at the rural site. A positive matrix factorization analysis was performed to quantify the impact of different mixing states on Eabs. Our results showed a small Eabs (1.06-1.11) for BC particles from fresh primary emissions, while the Eabs increased significantly above 1.3 when BC was aged rapidly with increased coatings of OC-nitrate or nitrate; it can reach above 1.4 as sulfate was involved in BC aging.