We report the synthesis of N,N′-Bis(hexyl)-1,7-di(thiophenyl)perylene-3,4:9,10-tetracarboxylic acid diimide (T-PDI-H) based small molecule by Suzuki coupling method for organic photovoltaic (OPV) application. The synthesized small molecule was confirmed by FT-IR and NMR techniques. The T-PDI-H showed broad and strong absorption in the UV-Visible region. From UV-Visible spectra we observed a low optical band gap (Eoptg) of 1.96 eV for T-PDI-H. From the cyclic voltammetry, the calculated HOMO, LUMO and electrochemical band gap (Eeleg) for the small molecule was −5.77, −3.44 and 2.33 eV respectively. Thermogravimetric analysis was employed to elucidate the thermal stability of T-PDI-H small molecule, it showed good thermal stability up to 400 °C. The preferred property for the high power conversion efficiency (PCE) OPV device, molecule must possess broad and strong absorption in the UV-Vis region, low band gap, and high thermal and environmental stability. T-PDI-H small molecule might satisfy the above standards with the chance to give maximum power conversion efficiency (PCE).
CITATION STYLE
Ganesamoorthy, R., Sathiyan, G., Thangamuthu, R., & Sakthivel, P. (2017). Synthesis and characterization of bay substituted perylene diimide small molecule for organic solar cell application. In Springer Proceedings in Physics (Vol. 189, pp. 401–415). Springer Science and Business Media, LLC. https://doi.org/10.1007/978-3-319-44890-9_37
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