Peroxides of the Group Two Elements of the Periodic Table

  • Vol’nov I
  • Petrocelli A
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Abstract

All elements of the second group, with the exception of beryllium [1], form peroxide compounds. Peroxides of calcium, strontium, and barium belong to the M2+O2 2- type; while peroxides of magnesium, zinc, and cadmium, of general formula MO2 {\textbullet} xH2O, probably belong to the HO---M---OOH type where the covalent bond between the hydroperoxyl group and the metal atom is the same as that in the hydrogen peroxide molecule [2--4]. Radium peroxide, RaO2, the heat of formation of which is estimated as 150 kcal/mole [5], has not yet been produced.

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Vol’nov, I. I., & Petrocelli, A. W. (1966). Peroxides of the Group Two Elements of the Periodic Table. In Peroxides, Superoxides, and Ozonides of Alkali and Alkaline Earth Metals (pp. 57–89). Springer US. https://doi.org/10.1007/978-1-4684-8252-2_4

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