The photodissociation of dibenzoyl peroxide is controlled by its S1-lifetime and in 0.4 ps leads to a benzoyloxy/phenyl radical pair plus CO2 via concerted bond breakage of the O-O and the phenyl-C(carbonyl) bond.
CITATION STYLE
Reichardt, C., Schäfer, T., Schroeder, J., VÖhringer, P., & Schwarzer, D. (2009). Ultrafast Photodecomposition of Dibenzoyl Peroxide studied by Time-Resolved Infrared Spectroscopy. In Springer Series in Chemical Physics (Vol. 92, pp. 490–492). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-540-95946-5_159
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