The thermal properties and the flammability of pigmented elastomeric materials: Part I. Phthalocyanine pigments

Abstract

This paper presents thermal properties of organic pigments such as zinc phthalocyanine and chloroaluminum phthalocyanine that were synthesized according to the literature data. These pigments were characterized by means of elementary analysis and measurements of particle size. They were then incorporated into butadiene-styrene rubber and butadiene-acrylonitrile rubber. The elastomeric mixtures were cross-linked by two methods: using organic peroxide or sulfur. The effect of phthalocyanines on the thermal properties, flammability, and fire hazard of the pigmented polymeric materials obtained as well as on their mechanical properties and cross-linking degree was studied. It has been shown that the phthalocyanine pigments not only impart appropriate esthetic values to the final goods but also increase their thermal stability and considerably reduce the flammability and fire hazard of elastomers and even make possible materials that are self-extinguishing under air atmosphere. These pigments also have a beneficial influence on the degree of cross-linking of the elastomers investigated and their mechanical properties. © Akadémiai Kiadó, Budapest, Hungary 2014.