Diagnostic of nanocomposite films formed by gold nanoparticles embedded in a polytetrafluorethylene matrix has been performed utilizing modulation polarization spectroscopy technique. The dependencies of annealing influence on morphology structure and LSPR parameters of Au-PTFE films were studied and discussed. Effective optical parameters of Au-PTFE films were obtained. Two types of LSPR were detected: the first is on isolated non-interacting Au NPs and the second – between Au NPs caused by dipole fields’ interactions. The experimental data were confirmed by theoretical calculations. Radiative and non-radiative modes of surface plasmons were studied. Plasma frequencies were obtained for Au-PTFE films with unheated structure and annealed at temperatures of 300 and 520 °C by measuring of spectral characteristics of the angle of isotropic reflection θp=0(λ).
CITATION STYLE
Maksimenko, L. S., Rudenko, S. P., Stetsenko, M. O., Matyash, I. E., Mischuk, O. M., Kolomzarov, Y. V., & Serdega, B. K. (2016). Diagnostic of resonant properties of Au-PTFE nanostructures for sensor applications. In NATO Science for Peace and Security Series A: Chemistry and Biology (pp. 267–280). Springer Verlag. https://doi.org/10.1007/978-94-017-7593-9_21
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