Enhanced Isopropyl Alcohol Conversion over Acidic Nickel Phosphate-Supported Zeolite Catalysts

Abstract

In this preliminary research, the catalytic activity of isopropyl alcohol conversion to diisopropyl ether through dehydration reaction catalyzed by zeolite-Ni and zeolite-Ni(H2PO4)2was comparatively described. The natural zeolite was treated with 1% HF and 6 N HCl prior to modifications using the impregnation method. Isopropyl alcohol conversion was examined at a mild temperature of 150 °C for 3.5 h on the reflux system with various catalyst loadings. X-ray diffraction and Fourier transform infrared analysis confirmed the successful impregnation of nickel and nickel phosphate into the zeolite. Scanning electron microscopy analysis revealed a cubic-like structure on zeolite-Ni(H2PO4)2, whereas homogenously distributed nickel species were observed on the zeolite-Ni catalyst. Energy-dispersive X-ray spectroscopy analysis reinforced the accomplishment of zeolite modifications. The N2physisorption isotherms showed a decline in the surface area and total pore volume of the zeolite because of the blocking of pores. The zeolite-Ni(H2PO4)2catalyst had higher acidity than unmodified zeolite and zeolite-Ni catalysts, which inherently suggested that the presence of phosphate groups results in higher catalytic activity toward isopropyl alcohol. The highest catalytic activity was attained by 8 mEq/g metal loading zeolite-Ni(H2PO4)2with isopropyl alcohol conversion of 81.51%, diisopropyl ether yield, and selectivity of 40.77 and 33.16%. The reusability study suggested that the zeolite-Ni(H2PO4)2catalyst was still active and had sufficient catalytic activity stability toward isopropyl alcohol after the third cycle was reused. This nickel phosphate-based modified zeolite was adequately potential for diisopropyl ether production through isopropyl alcohol dehydration.