A one-step, modular route to optically-active diphos ligands

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Abstract

A chlorosilane elimination reaction has been developed that allows the efficient synthesis of optically pure C1-symmetric, C1-backboned diphosphines with a wide variety of stereoelectronic characteristics.

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Louise Hazeland, E., Chapman, A. M., Pringle, P. G., & Sparkes, H. A. (2015). A one-step, modular route to optically-active diphos ligands. Chemical Communications, 51(50), 10206–10209. https://doi.org/10.1039/c5cc03517a

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