Abstract
The present study deals with the obtaining of solid cerium by molten salt electrolysis of a 46.74 - 48.26 - 5wt% LiF-NaF-NaCeF4 mixture, in the temperature range 700 - 730 °C and with a current efficiency of ∼75%. For this purpose NaCeF4 was obtained, characterized and it's cubic form was identified. The solubility and decomposition potential of this compound in the molten electrolyte 49.2 - 50.8% LiF-NaF was also studied.
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Constantin, V., Popescu, A. M., & Zuca, S. (2003). Preliminary studies of the obtaining of solid metallic cerium from fluoride melts. Zeitschrift Fur Naturforschung - Section A Journal of Physical Sciences, 58(1), 57–62. https://doi.org/10.1515/zna-2003-0109
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