Novel organophosphorus cage compound produced by an unexpected oxidative coupling of 1,2,4-triphosphole: Crystal and molecular structures of two isomers of formula P6C4But4CHSiMe3

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Abstract

Reaction of Li(P3C2But2 with BrCH(SiMe3)2 results in a novel organophosphorus compound with the formula, P6C4But4CHSiMe3 (1). Compound 1 was fully characterised spectroscopically and its unique molecular structure determined by single crystal X-ray diffraction. Another isomer (2) with a saturated structure was also fully characterised.

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Araujo, M. H., Rajão, D. A., Doriguetto, A. C., Ellena, J., Castellano, E. E., Hitchcock, P. B., & Caliman, V. (2002). Novel organophosphorus cage compound produced by an unexpected oxidative coupling of 1,2,4-triphosphole: Crystal and molecular structures of two isomers of formula P6C4But4CHSiMe3. Journal of the Brazilian Chemical Society, 13(5), 555–558. https://doi.org/10.1590/S0103-50532002000500002

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