A kinetic study on the oxidation of indole by peroxomonosulphate in acetonitrile solvent

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Abstract

Kinetics of oxidation of indole by peroxomonosulphate (PMS) in aqueous acetonitrile medium has been investigated. The reaction follows a total second order, first order each with respect to [Indole] and [PMS]. The rate of the reaction was not affected by added [H+]. Variation of ionic strength (ì) had no influence on the rate. Increase of percentage of acetonitrile decreased the rate. Absen ce of any polymerization indicated a nonradical pathway. Activation and thermodynamic parameters have bee n computed. A suitable kinetic scheme based on these observations is proposed. The reactivity of PMS towards Indole was found to be higher than that with peroxodisulphate.

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APA

Kavery, M., Govindasamy, C., & Johnson, S. (2013). A kinetic study on the oxidation of indole by peroxomonosulphate in acetonitrile solvent. Journal of the Korean Chemical Society, 57(2), 210–215. https://doi.org/10.5012/jkcs.2013.57.2.210

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