Hydrophilic Antimicrobial Polyethersulfone Membrane for Removal of Turbidity of Well-Water

Abstract

Membrane-based technologies have been widely used for surface water treatment. Yet, many aspects of this technology can still be improved. This study aims to develop polyethersulfone (PES)-based phase-inverted membranes to improve the morphological structure, antimicrobial properties, and performance by incorporating Poloxamer 188 and patchouli oil as the dope solution additives. The performance of the membrane was assessed for filtration of well water and by evaluating the turbidity rejection. This study used a phase inversion technique in the membrane manufacturing process with PES, PES + P188 + 1 wt% PO, PES + P188 + 3 wt% PO, and PES + P188 + 7 wt% PO. The characteristics of the obtained membranes were studied in terms of structure and morphology, microbial growth prevention, hydrophilicity, filtration flux, and ability to reduce the turbidity of well water samples. Results show that the addition of Poloxamer 188 and patchouli oil in the dope solution turned the membrane more porous (up to 73.24% increase in porosity) and more hydrophilic (the water contact angle (WCA) was lowered from 70 to 37°). The additives also increased the antibacterial properties of the membrane, as shown by up to 97.5% reducing Escherichia coli colonies on the membrane surface. Overall, the results demonstrate significant improvements in the characteristics and performance of PES membranes by incorporating Poloxamer 188 co-polymer and patchouli oil as additives in the dope solution. The modified membrane was successfully applied to remove turbidity from a water sample. The turbidity parameters in well water samples could be fully reduced in nine out of ten samples by the membrane containing 7 wt% PO additives.